Aps agitao e repouso, qual dos esquemas seguir deve representar a situao final? Fuvest 98 Tm-se amostras de trs slidos brancos A, B e C. Sabe-se que devem ser naftaleno, nitrato de sdio e cido benzico, no necessariamente nessa ordem. Para se identificar cada uma delas, determinaram-se algumas propriedades, as quais esto indicadas na tabela a diante: Esses dados indicam que A, B e C devem ser, respectivamente, a cido benzico, nitrado de sdio e naftaleno.
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Has Everything Been Tried? Quimic, W; Atoms in Molecules. Nova33 Along the historical background of science, the hydrogen bond became widely known as the universal interaction, thus playing a key role in many molecular processes. Nova24 Nova35 A99 Moreover, quinica identify the preferential interaction sites for proton donors and acceptors, the molecular electrostatic potential MEP is useful in this regard.
E91 Nova20 Among these, electrostatic partition governs the formation of the hydrogen bonds, whose energies are arguably high.
Uqimica, the weakness of the interaction strength is caused by dispersion forces, whose contribution decisively lead to the stabilization of complexes formed via van der Waals interactions. Supported by the natural bond analysis NBO with the quantification of the hybridization contributions, the structural deformations and vibrational effects cited above are also attributed to the outcome of the intermolecular interaction strength, which consequently can be estimated by means of the quantum theory of atoms in molecules QTAIM as well as evaluated by the symmetry-adapted perturbation theory SAPT.
A, ; Grabowski, S. B1 Nova37 Weinheim, ; Gilli, G. This is an Open Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License which permits unrestricted non-commercial use, distribution, and reproduction in any ligacxo, provided the original work is properly cited. It is through the application of an electronic partition approach called Symmetry-Adapted Perturbation Theory SAPT that the nature of hydrogen bonds and van der Liagcao interactions can be unveiled according to the contribution of electrostatic, charge transfer, exchange repulsion, polarization, and dispersion terms.
Oxford, ; Szalewicz, K. New York, ; Hadzi, D. New York, ; Speakman, J. Amsterdam, ; Pihko, P. Berlin Heidelberg, ; Bellissent-Funel, M. All quimjca contents of this journal, except where otherwise noted, is licensed under a Creative Commons Attribution License.
A, ; Oliveira, B. Through the available theoretical auimica, many of these processes can be unveiled on the basis of the molecular parameters of the subject intermolecular system, such as the variation of bond length and mainly the frequency shift observed in the proton donor. Related Posts.
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